How do you find Polarity?

1 Answer
Feb 21, 2018

Uneven dipole moments in an asymmetrical molecule...

Explanation:

Polarity happens when a molecule has a partially positive end and a partially negative end. This happens when the bond between atoms has a big electronegativity difference.

For example, in ammonia #(NH_3)#, the nitrogen has an electronegativity of #3.04#, while hydrogen has only an electronegativity of #2.2#. The difference #(DeltaEN=0.84)# is actually quite a lot, so hydrogens' electrons get pulled towards nitrogen's nucleus, leaving the hydrogens a positive charge on one end, while the lone unpaired electrons on the nitrogen form a negative charge on the other end.

Here is a picture:

https://www.quora.com/Why-is-NF3-less-polar-than-NH3

As you can see here, the nitrogen pulls the hydrogens' electrons, which therefore leaves a positive charge on one end of the molecule (the hydrogens), and a negative charge on the other end (the lone electrons of nitrogen).