Which type of reaction is AlCl_3 + 3 KOH ->Al(OH)_3+ 3 KCl?

2 Answers
Aug 7, 2018

A double replacement reaction

Explanation:

none of the atoms or polyatomic ions change the oxidations states, so it is not a oxidation reduction reaction.

The reaction follows the general form of a double replacement

A^+B^- (+) C^+ D^-= A^+ D^- (+ ) C^+ B^-
The positive three ion of Al disassociates with the Chlorine -1 ion.
then the still positive +3 ion of Al then combines with the -1 OH

The positive +1 K disassociates with the Hydroxide ion -1 ion then the still positive +1 K ion combines with the -1 Chlorine ion.

This is a classic example of a double replacement reaction.

Aug 7, 2018

This is a double replacement (double displacement) reaction.

Explanation:

In a double replacement reaction, the cations in two compounds switch places. The generic reaction is:

color(red)"A"color(green)"X" + color(blue)"B"color(purple)"Y""rarrcolor(blue)"B"color(green)"X" + color(red)"A"color(purple)"Y",

where color(red)"A" and color(blue)"B" are the cations and color(green)"X" and color(purple)"Y" are the anions.

One of the products of a double replacement reaction must be water (neutralization), an insoluble gas (such as "H"_2" or "CO"_2", or a precipitate (an insoluble solid).

color(red)"Al"color(green)("Cl")_3("aq") + 3color(blue)"K"color(purple)("OH")("aq)"rarr"3"color(blue)("K")color(green)("Cl") + color(red)("Al")(color(purple)("OH"))"_3

When the aqueous "AlCl"_3" and aqueous "KOH" solutions are mixed, an insoluble solid is produced. We can see that neither of the products is water or an insoluble gas, but one of the products is a precipitate because it is insoluble in aqueous solutions.

We can find out which product is the precipitate by consulting a solubility table like the one below. We can see that compounds containing alkali metal cations, such as "K"^(+)", are soluble in aqueous solutions. We can also see that compounds that contain the hydroxide ion, "OH"^(-)", are insoluble, and aluminum is not one of the exceptions. Therefore, the precipitate is the compound "Al(OH)"_3".

The entire equation with physical states included is:

"AlCl"_3("aq") + "3KOH(aq)"rarr"Al(OH)"_3("s") + "3KCl(aq)"

We can use a down arrow to show that the solid is a precipitate.

"AlCl"_3("aq") + "3KOH(aq)"rarr"Al(OH)"_3darr + "3KCl(aq)"

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