Question #53f3b

1 Answer
Jan 5, 2015

Since most solids have periodic arrays of atoms that form crystal lattices, which must imply a degree of symmetry in the arrangement of these lattices.

An ideal crystal can be considered to be a repetition of identical structures in 3D space. Lattices are mathematical points set at specific coordonates in space that can describe the periodicity of such a repetitive structure. Atoms, which are placed in specific lattice points, represent the identical structural units.

All possible lattices can be described by a set of three linearly independent vectors, veca_1a1, veca_2a2, and veca_3a3 - these represent the unit vectors of the lattice.

Every lattice point can be described by a translation of a vector vecRR described by

vecR = n_1 * veca_1 + n_2 * veca_2 + n_3 * veca_3R=n1a1+n2a2+n3a3,

where n_1n1, n_2n2, and n_3n3 are integers.

So, a Bravais lattice represents an infinite array of discrete points that have an arrangement and an orientation that appear exactly the same from whichever point the array is viewed.

14 Bravais lattices are commonly used to classify lattice structures according to basic symmetry groups.

http://www.seas.upenn.edu/~chem101/sschem/solidstatechem.htmlhttp://www.seas.upenn.edu/~chem101/sschem/solidstatechem.html

Each Bravais lattice is obtained by a specific vecRR. For example, simple cubic is obtained when a_1 = a_2 = a_3a1=a2=a3 and the angles between the three vectors are all equal to 90^@90, as you can see here:

http://www.seas.upenn.edu/~chem101/sschem/solidstatechem.htmlhttp://www.seas.upenn.edu/~chem101/sschem/solidstatechem.html

(Here aa, bb, and cc were used instead of a_1a1, a_2a2, and a_3a3; alphaα, betaβ, and gammaγ represent the angles between the three unit vectors).

Here's a video showing all the 14 Bravais lattice structures: