How many electrons have...?

#a)# #n = 4#, #l = 2#
#b)# #n = 4#, #l = 2#, #m_l = +2#
#c)# #n = 4#, #l = 2#, #m_l = +2#, #m_s = +1/2#

1 Answer
Mar 10, 2015

The answers would be a) 10 electrons, b) 2 electrons, and c) 1 electron.

I assume you're familiar with quantum numbers, so I won't go into too much detail about them.

So, here are the four quantum numbers you have to work with

http://figures.boundless.com

Let's start with point a). Since you already know that n = 4 and l = 2, you only have to decide the possible values for the magentic quantum number, #m_l#, and for the spin quantum number, #m_s#.

Since the magnetic quantum number can only go from #-l# to #+l#, you'll have these values for #m_l#

#m_l = -2, -1, 0, +1, +2#

SInce each of these orbitals can hold a maximum of two electrons, one having spin-up and one having spin-down, a total of 10 electrons can share the quantum numbers n = 4 and l = 2

#m_l = -2 => m_s = +- 1/2#

#m_l = -1 => m_s = +- 1/2#

#m_l = 0 => m_s = +- 1/2#

#m_l = +1 => m_s = +- 1/2#

#m_l = +2 => m_s = +- 1/2#

On to point b). Now you know that n = 4, l = 2, and #m_l# = 2, which means that only 2 electrons, one having spin-up and one having spin-down, can share these three quantum number values.

#m_s = +- 1/2#

FInally, point c). Because every electron has a specific set of quantum numbers that describes its position around the nucleus, the values given to you for all the four quantum numbers can only describe 1 electron.