Question #55028

1 Answer
May 17, 2015

You'd need 0.500 ML in order to precipitate that much magnesium from your solution.

Start with the balanced chemical equation for this double replacement reaction

#MgCl_(2(aq)) + color(red)(2)NaOH_((aq)) -> Mg(OH)_(2(s)) darr + 2NaCl_text((aq])#

This reaction will form sodium chloride, a soluble salt, and magnesium hydroxide, an insoluble solid that will precipitate out of the solution.

Notice the #1:color(red)(2)# mole ratio that exists between magnesium chloride and sodium hydroxide. This tells you that, for every 1 mole of magnesium chloride, you need #color(red)(2)# moles of sodium hydroxide in order for all of the magnesium to be removed from the solution.

So, you know that you're dealing with a 1.00-ML, 0.0500-mol/L solution of magnesium chloride.

Use the solution's molarity to determine how many moles of magnesium chloride you have

#C = n/V => n = C * V#

#n_(MgCl_2) = 0.0500"mol"/cancel("L") * 1.0 * 10^(-6)cancel("L") = 0.0500 * 10^(-6)"moles"# #MgCl_2#

Use the aforementioned mole ratio to determine how many moles of sodium hydroxide you'd need

#0.0500 * 10^(-6)cancel("moles"MgCl_2) * (color(red)(2)"moles"NaOH)/(1cancel("mole"MgCl_2)) = 0.100 * 10^(-6)"moles"# #NaOH#

Since you know the molarity of the sodium hydroxide solution, you can determine the volume you'd need by

#C = n/V => V = n/C#

#V_(NaOH) = (0.100 * 10^(-6)"moles")/(0.200cancel("mol")/"L") = 0.5 * 10^(-6)"L"#

This is equivalent to having

#0.5 * 10^(-6)cancel("L") * "1 ML"/(10^(-6)cancel("L")) = color(green)("0.5 ML")#

SIDE NOTE Here's how the net ionic equation looks like for your reaction

#Mg_((aq))^(2+) + 2OH_((aq))^(-) -> Mg(OH)_(2(s)) darr#