How many electrons have n = 3n=3, m_l = 0ml=0, and m_s = +1/2ms=+12?

1 Answer
Oct 4, 2015

Three electrons.

Explanation:

The idea here is that each electron in an atom has an unique set of quantum numbers, which describes exclusively that electron.

The four quantum numbers are

![http://socratic.org/questions/what-are-quantum-numbers](useruploads.socratic.org)

In your case, the only quantum number that is not accounted for is the angular momentum quantum number, ll, which can take values from 00 to (n-1)(n1), where nn is the principal quantum number.

So, the question wants you to find the number of electrons that

  • can be located on the third energy level, since n=3n=3;
  • can be located in an orbital that has a specific orientation, since m_l=0ml=0
  • have spin-up, since m_s = +1/2ms=+12

Start by finding how many orbitals can accomodate these electrons. SInce you know what the relationship of ll is to nn, you can say that

l = 0, 1, ..., (n-1) implies l = {0; 1; 2}

For l=0, which corresponds to the s-orbital, you can have one electron located in the 3s-orbital that has spin-up.

For l=1, which corresponds to the 3p-orbitals, you can have an electron located in the 3p_y orbital, for which m_l=0, that has spin-up.

Finally, for l=2, which corresponds to the 3d-orbitals, you can have an electron located in the 3d_(yx), which would correspond to m_l=0, that has spin-up.

Therefore, these quantum numbers can correspond to a total of three electrons

  • n=3" " l=0" "m_; = 0" "m_s = +1/2
  • n=3" "l=1" "m_l = 0" "m_s = +1/2
  • n=3" "l=2" "m_l = 0" "m_s = +1/2