What does valence bond theory not account for that molecular orbital theory does successfully?

Jun 26, 2017

Valence bond theory (VB theory), or at least the textbook version, does not mention delocalization of electron density, describing covalent bond formation as due to maximum overlap.

What VB theory does instead is that it specifies only a single state: the one that describes the bonded molecule with localized electrons (situated between atoms, but not spread throughout the molecule).

COMPARISON WITH MO THEORY

It can be thought of as a simpler view than molecular orbital theory (MO theory), which extends the premise of VB theory by proposing the delocalization of electron density throughout the molecule.

You instead have multiple states shown in so-called molecular orbital diagrams that each contribute to the overall description of the molecule.

Take the very simple example of ${\text{H}}_{2}$:

In this, the antibonding MO has no contribution in isolation, because no electrons are in it. In a scenario where ${H}_{2}$ accepts electrons from, say, a transition metal, then we start talking about the antibonding MO. (But it was always there!)

ANALOGY WITH RESONANCE STRUCTURES

The MOs in the middle are roughly analogous to individual resonance structures (see A, B, and C below), in the sense that they are single states that average to provide a full description of the molecule (at least, when it's not reacting).

A, B, and C are resonance contributors; D is the resonance hybrid structure.

Comparing with resonance structures, the molecule as a whole, while not reacting, is then analogously described by the resonance hybrid structure, an averaged configuration of multiple resonance structure contributors.

In three dimensions, MO theory then describes the molecule by an averaged configuration of molecular orbitals, including how the molecule behaves while it reacts.