How do we utilize Lewis structure in simple species such as nitrate ion?

1 Answer
Apr 4, 2017

Lewis structure is simply electron counting..........

Explanation:

Let's take the nitrate, anion, NO3. Nitrogen comes from Group 15, and has five valence electrons, oxygen comes from Group 16, and has six valence electrons.

And thus we have to distribute 5+3×6+1=24 electrons around the nitrate core...........Why did I add an extra electron?

And thus, O=N+(O)2, distributes 6, 4, and 2×7 valence electrons around O=, N, and O respectively, and this (with the 2 inner core electrons) accounts for the charge on the atom, neutral, positive, or negative: i.e. N,Z=7;O,Z=8.

As always, the charge on the atom is the difference between the nuclear charge, and the electronic charge. For more of the same see [here.](https://socratic.org/questions/what-is-the-formal-charge-of-n-in-hno-3)

What about NH3, and NH+4?