# Valence Electrons

Lewis Structures of Atoms - Mr Pauller

Tip: This isn't the place to ask a question because the teacher can't reply.

## Key Questions

• Valence electrons are the electrons present in the outermost shell of an atom.

You can easily determine the number of valence electrons an atom can have by looking at its Group in the periodic table.

For example, atoms in Groups 1 and 2 have 1 and 2 valence electrons, respectively.

Atoms in Groups 13 and 18 have 3 and 8 valence electrons, respectively.

Valence electrons are responsible for the reactivity of an element. They determine how "willing" the elements are to bond with each other to form new compounds. If the valence shell of an element is full, such as with a noble gas, then the element does not want to gain or lose an electron.

For example, alkali metals, which all have a valency of 1, want to lose that one electron and are likely to form ionic bonds (such as in the case of NaCl, or table salt) with a Group 17 element, which has a valency of 7 and wants to gain that one electron from the alkali metal (Group 1 element) to form a stable valency of 8.

For more on valence electrons and how they're related to the periodic table, I strongly recommend this video:

Citations: Tyler Dewitt. (2012, December 18) Valence Electrons and the Periodic Table [Video File].

• The valence electrons are the electrons that determine the most typical bonding patterns for an element.

These electrons are found in the s and p orbitals of the highest energy level for the element.

Sodium $1 {s}^{2} 2 {s}^{2} 2 {p}^{6} 3 {s}^{1}$
Sodium has 1 valence electron from the 3s orbital

Phosphorus $1 {s}^{2} 2 {s}^{2} 2 {p}^{6} 3 {s}^{2} 3 {p}^{3}$
Phosphorus has 5 valence electrons 2 from the 3s and 3 from the 3p

Lets take the ionic formula for Calcium Chloride is $C a C {l}_{2}$

Calcium is an Alkaline Earth Metal in the second column of the periodic table. This means that calcium ${s}^{2}$ has 2 valence electrons it readily gives away in order to seek the stability of the octet. This makes calcium a Ca+2 cation.

Chlorine is a Halogen in the 17th column or ${s}^{2} {p}^{5}$ group.
Chlorine has 7 valence electrons. It needs one electron to make it stable at 8 electrons in its valence shells. This makes chlorine a Cl^(−1) anion.

Ionic bonds form when the charges between the metal cation and non-metal anion are equal and opposite. This means that two Cl^(−1) anions will balance with one $C {a}^{+ 2}$ cation.

This makes the formula for calcium chloride, $C a C {l}_{2}$.

For the example Aluminum Oxide $A {l}_{2} {O}_{3}$

Aluminum ${s}^{2} {p}^{1}$ has 3 valence electrons and an oxidation state of +3 or $A {l}^{+ 3}$
Oxygen ${s}^{2} {p}^{4}$ has 6 valence electrons and an oxidation state of -2 or O^(−2)

The common multiple of 2 and 3 is 6.
We will need 2 aluminum atoms to get a +6 charge and 3 oxygen atoms to get a -6 charge. When the charges are equal and opposite the atoms will bond as $A {l}_{2} {O}_{3}$.

In molecular (covalent) compounds these same valence electrons are shared by atoms in order to satisfy the rule of octet.

SMARTERTEACHER

The number of electrons in an atom's outermost valence shell governs its bonding behaviour.

#### Explanation:

The valence electrons are the electrons in the outermost electron shell of an atom.

That is why elements whose atoms have the same number of valence electrons are grouped together in the Periodic Table.

Generally, elements in Groups 1, 2, and 13 to 17 tend to react to form a closed shell, corresponding to the electron configuration ${s}^{2} {p}^{6}$.

This tendency is called the octet rule, because the bonded atoms have eight valence electrons.

METALS

The most reactive kind of metallic element is a metal from Group 1 (e.g., sodium or potassium).

An atom in Group 1 has only a single valence electron. This one valence electron is easily lost to form a positive ion with an ${s}^{2} {p}^{6}$ configuration (e.g., ${\text{Na}}^{+}$ or ${\text{K}}^{+}$).

A metal from Group 2 (e.g., magnesium) is somewhat less reactive, because each atom must lose two valence electrons to form a positive ion (e.g., ${\text{Mg}}^{2 +}$ with an ${s}^{2} {p}^{6}$ configuration.

Within each group of metals, reactivity increases as you go down the group.

The valence electrons are less tightly bound and easier to remove, because they are farther away from the nucleus of the atom.

NONMETALS

A nonmetal tends to attract additional valence electrons to attain a full valence shell.

It can either share electrons with a neighboring atom to form a covalent bond or it can remove electrons from another atom to form an ionic bond.

The most reactive kind of nonmetal is a halogen such as fluorine or chlorine.

It has an ${s}^{2} {p}^{5}$ electron configuration, so it requires only one additional valence electron to form a closed shell.

To form an ionic bond, a halogen atom can remove an electron from another atom in order to form an anion (e.g., $\text{F"^"-", "Cl"^"-}$, etc.).

To form a covalent bond, one electron from the halogen and one electron from another atom form a shared pair (e.g., in $\text{H–F}$, the dash represents a shared pair of valence electrons, one from $\text{H}$ and one from $\text{F}$).

Within each Group of nonmetals, reactivity decreases from top to bottom, because the valence electrons are at progressively higher energies and the atoms do not gain much stability by gaining electrons.

In fact, oxygen (the lightest element in Group 16) is more reactive than chlorine, even though it is not a halogen, because the valence electrons of oxygen are closer to the nucleus (at a lower energy).

Therefore, a metal from the bottom of Group 1 (like potassium) and a nonmetal from the top of Group 17 (like fluorine) will react violently, because they both benefit greatly from the reaction.

$\text{K}$ loses one electron to $\text{F}$ and forms the ionic compound potassium fluoride, $\text{K"^"+""F"^"-}$.

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