Question #d2b4f

1 Answer
Oct 7, 2017

The answer is indeed (B) "203 g"203 g.

Explanation:

The first thing that you need to do here is to figure out how much heat is being given off when "30.1 g"30.1 g of steam, presumably at 100^@"C"100C, are being converted to "30.1 g"30.1 g of liquid water at 100^@"C"100C.

To do that, you can use the standard molar enthalpy of vaporization of water, DeltaH_"vap"^@, which tells you how much heat is being given off when 1 mole of water is converted from steam at 100^@"C" to liquid water at 100^@"C", at standard pressure.

So, use the molar mass of water to convert the mass of steam to moles

30.1 color(red)(cancel(color(black)("g"))) * ("1 mole H"_2"O")/(18.015color(red)(cancel(color(black)("g")))) = "1.671 moles H"_2"O"

You can thus say that condensing "30.1 g" of steam at 100^@"C" to lqiuid water at 100^@"C" will give off

1.671 color(red)(cancel(color(black)("moles H"_2"O"))) * "40.7 kJ"/(1color(red)(cancel(color(black)("mole H"_2"O")))) = "68.01 kJ"

Now, the specific heat of water tells you how much heat is needed to increase the temperature of "1 g" of water by 1^@"C".

More specifically, you know that in order to increase the temperature of "1 g" of water by 1^@"C", you need to provide the sample with "4.184 J" of heat.

In your case, you need to change the temperature of the sample by

100.0^@"C" - 20.0^@"C" = 80.0^@"C"

so start by calculating how much heat would be needed to do that for a given mass of water.

80.0 color(red)(cancel(color(black)(""^@"C"))) * "4.184 J"/("1 g" * 1color(red)(cancel(color(black)(""^@"C")))) = "334.72 J g"^(-1)

This tells you that in order to increase the temperature of "1 g" of water by 80.0^@"C", you need to supply the sample with "334.72 J" of heat.

This means that the heat given off by the steam -> liquid phase change will be enough to heat--remember that "1 kJ" = 10^3 "J"

68.01 * 10^3 color(red)(cancel(color(black)("J"))) * overbrace("1 g"/(334.72 color(red)(cancel(color(black)("J")))))^(color(blue)("for an increase of 80.0"^@"C")) = color(darkgreen)(ul(color(black)("203 g")))

The answer is rounded to three sig figs.