How do you draw enantiomers with perspective formula?

1 Answer
Jul 26, 2015

You interconvert any two groups on the chiral carbons.

Explanation:

For example, the structure of 2-brombutane is

2BrBu

We can convert this to its enantiomer by interchanging any two groups.

We often interchange the groups on the wedges and dashes, as below.

WD Interconvert

It is not immediately obvious that these are mirror images of each other.

If we rotate the top structure 180 ° about the axis and put it below our original structure, we get

Rotated

The red line represents a mirror plane that shows the enantiomers.

It is often easier to interconvert the bonds in the plane of the paper. This gives us

Solid Interconvert

Here, the red line represents a vertical mirror plane with the two enantiomers.

There are other possibilities.

It just shows that we must practice viewing molecules in three dimensions.