Substitute #y=x^3# (note that when #x\to 0#, also #x^3# and thus #y# tend to 0, so it's a good substitution).
Write down the McLaurin series for #arctan(y)#, which is known: it's the sum, with alternate sign, of the odd powers of #y# divided by the power itself:
#y-y^3/3+y^5/5-y^7/7+y^9/9+...#,
or in a compact way,
#sum_{i=0}^infty (-1)^{n} y^{2n+1}/{2n+1}#
Now substitute back #y=x^3#:
#sum_{i=0}^infty (-1)^{n} (x^3)^{2n+1}/{2n+1}=
sum_{i=0}^infty (-1)^{n} x^{6n+3}/{2n+1}#
Multiply the whole expression by #x^2#:
#sum_{i=0}^infty (-1)^{n} x^2*x^{6n+3}/{2n+1}=
sum_{i=0}^infty (-1)^{n} x^{6n+5}/{2n+1}#