How does electronegativity affect boiling point?
1 Answer
Compounds that have hydrogen atoms bound to strongly electronegative atoms tend to have disproportionately high boiling points.
Explanation:
The cases in point are
This charge separation, this polarity, is an additional INTERMOLECULAR force that binds molecules together, and must be overcome before the molecules enter the gas phase. The boiling point of water far exceeds that of its Group VI congeners, hydrogen sulfide, and hydrogen selenide; which are are room temperature gases.
Note also that ammonia (while this is a gas at RT) also has an unusually high boiling point, at