What are geometrical isomers?

1 Answer
Jul 8, 2016

These are isomers with identical connectivity, but different geometry, i.e. different spatial arrangement,

Explanation:

Consider #2-"butene"#; the pendant methyl groups can be on the same side of the olefinic bond to give the #"cis"# isomer, or on opposite sides of the olefin to give the #"trans"# isomer.

The key word is #"connectivity"#. In both isomers of #"2-butene"# #C_1# connects to #C_2# connects to #C_3# connects to #C_4#. Nevertheless, for #"2-butene"# we can draw geometric isomers that preserve this connectivity, but nevertheless have distinct geometries given the disposition across the olefinic bond.