What is the bond angle in a water molecule?

1 Answer
Nov 15, 2015

104.4776

You can derive the approximate angle by knowing that the oxygen in water has four electron groups, giving it a tetrahedral electron geometry, and a bent molecular geometry.

From knowing that it has a tetrahedral electron geometry, but two lone pairs of electrons, one question should pop into your mind:

"Why does water not have a 109.5 H-O-H bond angle? "

It's because the two nonbonding 2p orbitals on oxygen impose a spatial repulsion, bending together the two hydrogens and decreasing the bond angle, which is measured such that it is 180.

![chemwiki.ucdavis.edu)

(It is acceptable to just say 104.5, but it is known to more decimal places than just one.)