Why is ethylene planar?

1 Answer
Oct 8, 2016

There is no rotation about the axis joining the 2 carbon atoms, therefore ethylene is a planar molecule.

Explanation:

The diagram below shows the bonding of ethylene molecule.

wps.prenhall.com/wps/media/objects/3311/3391094/imag0906/AAAVJKW0.JPGwps.prenhall.com/wps/media/objects/3311/3391094/imag0906/AAAVJKW0.JPG

The pp-orbitals are perpendicular to the plane. All the rest of the sigmaσ bonds are on the plane.

The molecule cannot be twisted without breaking the piπ bond, as the pp-orbital needs to remain parallel with each other.