How does ammonium hydroxide react with sulfuric acid?

2 Answers
May 18, 2017

Please notice that the anions swap places from the left side to the right side; this makes it a Double Displacement reaction.

May 18, 2017

This is an acid base reaction...........

Explanation:

When we write #NH_4OH#, i.e. #"ammonium hydroxide"#, we really mean #H_3N*OH_2#, i.e. aqueous ammonia. Concentrated ammonia solution in water (the type that is retailed) is approx. #15*mol*L^-1# with respect to ammonia.

Now of course, as a weak base, there is SOME ammonium ion in solution according to the following equilibrium:

#NH_3(aq) + H_2O(l) rightleftharpoons NH_4^+ + HO^-#,

but the equilibrium lies to the left, and the dominant species in solution is #NH_3(aq)#.

And so we could rewrite the reaction as:

#H_2SO_4(aq) + 2NH_3(aq) rarr 2NH_4^+ + SO_4^(2-)#.

We could isolate the salt #"ammonium sulfate"#, #(NH_4)_2SO_4# from such a solution. Ammonium sulfate is a ubiquitous agricultural fertilizer.