How do you draw the lewis structure for NO2?

2 Answers
Aug 5, 2018

Refer to the video in the explanation.

Explanation:

Aug 5, 2018

So how many valence electrons we got...?

Explanation:

Five from nitrogen, and 12 from the oxygen atoms...and so we got 8 and a HALF electron pairs to distribute...17 electrons in total

As is typical, the least electronegative atom is placed in the middle to give...

O=.N+O

From left to right as we face the page, each atom is associated with SIX, FOUR, and SEVEN valence electrons, giving rise to formal charges of 0, +1, and 1. Of course, we could write the other resonance structure...

O.N+=O

And so NO2 is a NEUTRAL, BENT molecule...whose geometry is based on a trigonal plane...ONO=120 to a first approx., but 115 in actuality....

Why don't you try it for nitrite ion, NO2...how does the Lewis structure evolve..?

And just to add, that the formal Lewis structure of NO2 is useful when we assess reactivity... NO2 can READILY dimerize (alternatively N2O4 can readily undergo dissociation.

(O)O=+.N++.N=O(O)(O)O=+.N+.N=O(O)

N2O4dinitrogen tetroxide

The nitrogen atom in NO2 or N2O4 is said to be quaternized, i.e. it bears a formal POSITIVE charge....