Question #485d5

1 Answer
May 18, 2015

The answer is A) V^(2+), U^(3+), Y^(3+).

http://imgur.com/k2U2nNqhttp://imgur.com/k2U2nNq

I'll give you the quick answer first, then focus more on explaining what's going on.

Right from the get-go, you can sahy that Y^(3+) wil be the weakest oxidizing agent. If you only use the information given to judge each cation's oxidizing strength, the fact that Y^(3+) cannot oxidize U placed it at the bottom of the stack.

By comparison, U^(3+) can oxidize one species, Y, and V^(2+) can oxidize two species, U and Y.

So there you have it

V^(2+) > U^(3+) > Y^(3+)

Now, here's what's going on. Since we've been working with standard electrode potentials, you can write the reduction half-reactions for U, V, and Y

U^(3+) + 3e^(-) rightleftharpoons U, E_U^@

V^(2+) + 2e^(-) rightleftharpoons V, E_V^@

Y^(3+) + 3e^(-) rightleftharpoons Y, E_Y^@

So, you start by placing Y in a solution that contains the U^(3+) cation and you observe that a reaction takes place. This means that U^(3+) oxidizes Y.

Automatically, E_U^@ must be more positive than E_Y^@, since U^(3+) can take electrons from Y. Keep this in mind

E_U^@ > E_Y^@

Now you place U in a solution that contains V^(2+) cations and you observe that a reaction takes place. The same thing that happensed before happens again.

V^(2+) oxidizes U, which must mean that

E_V^@ > E_U^@

Moving on. You place Y in a solution that contains V^(2+) cations, and the same thing happens again. V^(2+) oxidizes Y, which implies that

E_V^@ > E_Y^@

Finally, you place V in a solution that contains Y^(3+) and observe that the two don't react. This means that Y^(3+) cannot oxidize V, so

E_V^@ > E_Y^@

As you can see, it all comes down to solving the famous "if A is greater than B, and B is greater than C" inequalities. If you have

{ (E_U^@ > E_Y^@), (E_V^@ > E_U^@) :} => color(green)(E_V^@ > E_U^@ > E_Y^@)

So, if you have a standard electrode potential table listed from most positive to most negative, you'll get

V^(2+) + 2e^(-) rightleftharpoons V, E_V^@

U^(3+) + 3e^(-) rightleftharpoons U, E_U^@

Y^(3+) + 3e^(-) rightleftharpoons Y, E_Y^@

So, to summarize, you now know that

  • V^(2+) can oxidize anything lower and to the right of the equilibrium, in your case U and Y.;

  • U^(3+) can oxidize anything lower and to the right of the equilibrium, in your case Y;

  • Y^(3+) cannot oxidize anything higher and to the right of the equilibrium, in your case V.