Are angular nodes necessarily planes?

1 Answer
Apr 12, 2017

No, angular nodes can be nodal planes, but they can also be conical nodes. Angular nodes are more general, and nodal planes are an example.

Angular nodes are determined by finding what l corresponds to the orbital you are looking at.

https://saylordotorg.github.io/https://saylordotorg.github.io/

For example, a 3d orbital has l = 2, so it has two angular nodes. These happen to usually be nodal planes. For a 3d_(xy) orbital, these are the xz and yz planes.

However, for the 3d_(z^2) orbital, the two angular nodes correspond to the two conical nodes: the top half and the bottom half (these are at around 54.74^@ from the z axis).