Chromium has atomic number 24.
You can write its electron configuration as
#"[Cr] 1s"^2 color(white)(l)"2s"^2 "2p"^6 color(white)(l)"3s"^2 "3p"^6color(white)(l) "4s" color(white)(l)"3d"^5# or
#"[Cr] 1s"^2color(white)(l) "2s"^2 "2p"^6color(white)(l) "3s"^2 "3p"^6 "3d"^5color(white)(l)"4s"#
However you write it, you must remember that the #"3d"# orbitals have the highest energy and are filled last in the Aufbau process.
The quantum numbers of the first five #"3d"# electrons are
#bbul(ncolor(white)(m)lcolor(white)(m)m_lcolor(white)(m)m_s)#
#3color(white)(m)2color(white)(ml)"-2"color(white)(m)"+½"#
#3color(white)(m)2color(white)(ml)"-1"color(white)(m)"+½"#
#3color(white)(m)2color(white)(mll)0color(white)(m)"+½"#
#3color(white)(m)2color(white)(m)"+1"color(white)(m)"+½"#
#color(red)(3color(white)(m)2color(white)(m)"+2"color(white)(m)"+½")#
Thus, the quantum numbers of the last electron added to chromium are
#3, 2, "+2, +½"#.