Question #67208

1 Answer
Feb 7, 2015

Phosphorus is located in group 15 of the periodic table and has an atomic number equal to 15. This means that a neutral phosphorus atom has a total of 15 electrons.

The ground state electron configuration for phosphorus is

http://www.creative-chemistry.org.uk/alevel/module1/trends6.htm

#"P": 1s^(2) 2s^(2) 2p^(6) 3s^(2) 3p^(3)#

I'll use the noble gas shorthand notation from this point on.

#"P": ["Ne"] 3s^(2) 3p^(3)#

Now, an excited state configuration has one electron promoted from a lower to a higher energy level. Looking at the ground state configuration, you could have one electron from the #"3s"# sub-level promoted to the #"3p"# sublevel. The electron configuration will be

#"P": ["Ne"] 3s^(1) 3p^(4)#

Another possibility is to have one electron from the #"3p"# sub-level promoted to the #"4s"# sub-level

#"P": ["Ne"] 3s^(2) 3p^(2) 4s^(1)#

Yet another possibility is to have one electron from the #"3p"# sub-level promoted to the #"3d"# sub-level, skipping the #"4s"# sub-level altogether

#"P": ["Ne"] 3s^(2) 3p^(2) 3d^(1)#

Read more on how to determine excited state configurations here:

http://socratic.org/questions/how-do-you-determine-excited-state-electron-configuration