How many orbitals are in each sublevel?

1 Answer
Oct 19, 2015

That depends on the subshell.

Explanation:

Electrons that surround an atom's nucleus are distributed on specific energy levels, or shells.

Each shell is made up of a different number of subshells. More specifically, the number of subshells a shell can have increases as you move away from the nucleus.

![http://www.green-planet-solar-energy.com/http://electron-details.html](https://useruploads.socratic.org/KsEJYwAFRJGoF5cAe0Yh_layers-shells-blank.gif)

You can use quantum numbers to illustrate this point.

The principal quantum number, n, gives you the energy level, or shell.

Now, the number of subshells is given by the angular momentum quantum number, l, which can take values from 0 to n-1.

This means that you will have

  • n = 1 implies l = 0 -> the first shell only has one subshell, s
  • n = 2 implies l = 0, 1 -> the second shell has two subshells: s and p
  • n = 3 implies l = 0, 1, 2 -> the third shell has three subshells, sp, p, and d
    vdots

and so on.

The number of orbitals each subshell contains is given by the magnetic quantum number, m_l, which takes values from -l to l.

So, for example, how many orbitals would you say the 2p-subshell has?

Well, the 2p-subshell has l = 1, which means that m_l can be

m_l = {-1, 0, 1} -> the 2p-subshell contains 3 orbitals.

How about the 3d-subshell?

For the 3d-subshell, you know that l = 2. This means that m_l can be

m_l = {-2, -1, 0, 1, 2} -> the 3d-subshell contains 5 orbitals.

So, as a conclusion, you get th number of orbitals per subshell from the principal quantum number, n, which in turn gives you the value of the angular momentum quantum number, l.

The magnetic quantum number, the ones that tells you exactly how many orbitals you get per subshell, will always take values from -l to l, so if you know l, you automatically know m_l.