Question #e0dc9

1 Answer
Sep 11, 2017

The correct answer should be 624 hours (the data really only provides two significant figures).

Explanation:

This is a common nuclear chemistry problem. I’m not sure if it was correctly posted here.
The relationship between concentration and time for a first-order reaction (radioactive decay) is:
ln(([A]_t)/[A]_0)) = -ktln([A]t[A]0))=kt where [A] is the concentration at time (t) and k is the rate constant.

Half-life is t_(1/2) = 0.693/kt12=0.693k
A 10% reduction means that [A]_t/[A]_0 = 0.9[A]t[A]0=0.9, so ln(0.9) = -k xx 95ln(0.9)=k×95

-0.1054 = -k xx 950.1054=k×95 ; k = 0.1054/95 = 0.00111k=0.105495=0.00111
Half-life is t_(1/2) = 0.693/0.00111t12=0.6930.00111; t_(1/2) = 624.3t12=624.3 hours

CHECK:
ln(([A]_t)/[A]_0)) = -ktln([A]t[A]0))=kt ; ln(([A]_624.3)/[A]_0)) = -0.00111 xx 624.3ln([A]624.3[A]0))=0.00111×624.3
IF it is the correct half-life, [A]_624.3)/[A]_0[A]624.3)[A]0 = 0.5
ln(0.5) = -0.693ln(0.5)=0.693 ; -0.693 = -0.6930.693=0.693 CORRECT