An atom contains a total of 25 electrons. When the atom is in the ground state, how many different principal energy levels will contain electrons?

1 Answer
Jan 18, 2018

Well, with 25 electrons, whatever atom it is, it need not be neutral... but since it's within the neighborhood of a transition metal, we can assume it's one of them... i.e. it may be "Mn", or perhaps "Co"^(2+).


With 25 electrons, we can immediately write the electron configuration. Argon has 18 electrons and is the previous noble gas, and thus we use it as the noble gas core.

1s^2 2s^2 2p^6 3s^2 3p^6 3d^5 4s^2 -> [Ar] 3d^5 4s^2

And you can convince yourself that 18 + 5 + 2 = 25 electrons total.

This lands us in the first-row transition metals, and so we have involved bb(n = 1, 2, 3, ) and bb(n = 4). Those are the only principal energy levels involved... These contain the following orbitals:

n = 1: 1s
n = 2: 2s, 2p
n = 3: 3s, 3p, 3d
n = 4: 4s

We ignore the 4p, 4d, 4f obviously because they are empty.