What is sulfurous acid, and how does it relate to SO_2?

1 Answer
Oct 17, 2016

underbrace(SO_2(g))_"sulfur dioxide" + H_2O(l) rarr underbrace(H_2SO_3(aq))_"sulfurous acid"

Explanation:

Sulfur dioxide is the acid anhydride of sulfurous acid, i.e. H_2SO_3-=SO_2+H_2O. While sulfurous acid can be deprotonated, often we can treat it as water saturated with sulfur dioxide, i.e. as H_2O*SO_2 (which is of course formally H_2SO_3), The smell is sulfurous, but many people (including me!) find it pleasant, and antiseptic.