How do you know how to...?

(i) represent the complete oxidation of iron metal to ferric oxide?

(ii) represent the thermal decomposition of ferrous oxalate?

(iii) represent the disproportionation of ferrous oxide?

1 Answer
Jul 8, 2017

So how do you know? Got me.....?

Explanation:

Of course, you have to look at the context of the question......."Iron metal is heated under excess dioxygen gas for a "
"prolonged period........" Such conditions, would favour oxidation to "ferric iron".

2Fe(s) + 3/2O_2(g) +Delta rarrFe_2O_3(s)

On the other hand, "iron oxalate" can be thermally decomposed to "iron oxide" and "carbon dioxide" and "carbon monoxide".

FeC_2O_4(s)+Delta rarrFeO(s) + CO(g) + CO_2(g)

On the other, other hand, "ferrous oxide" could disproportionate to give iron metal and the mixed oxidation state "magnetite".....

3FeO(s) + DeltararrFe(s) + Fe_2O_3(s)

.........here Fe_2O_3 "aka magnetite" is a mixed oxidation state iron oxide.......FeO*FeO_2, i.e. an Fe(+IV) centre........

Depending where you are, you should be spoon-fed this info.