An atom contains a total of 25 electrons. When the atom is in the ground state, how many different principal energy levels will contain electrons?

1 Answer
Jan 18, 2018

Well, with #25# electrons, whatever atom it is, it need not be neutral... but since it's within the neighborhood of a transition metal, we can assume it's one of them... i.e. it may be #"Mn"#, or perhaps #"Co"^(2+)#.


With #25# electrons, we can immediately write the electron configuration. Argon has #18# electrons and is the previous noble gas, and thus we use it as the noble gas core.

#1s^2 2s^2 2p^6 3s^2 3p^6 3d^5 4s^2 -> [Ar] 3d^5 4s^2#

And you can convince yourself that #18 + 5 + 2 = 25# electrons total.

This lands us in the first-row transition metals, and so we have involved #bb(n = 1, 2, 3, )# and #bb(n = 4)#. Those are the only principal energy levels involved... These contain the following orbitals:

#n = 1#: #1s#
#n = 2#: #2s, 2p#
#n = 3#: #3s, 3p, 3d#
#n = 4#: #4s#

We ignore the #4p, 4d, 4f# obviously because they are empty.