How can aldehydes and ketones be prepared in the laboratory?

1 Answer
Oct 11, 2016

They are both oxidation product of alcohols.

Explanation:

We make a distinction between primary and secundary alcohols:

A primary alcohol has its OH group at the end of a carbon chain, so it looks like CH2OH (with two H's at the same C)
After oxidation this will look like CH=O and is called aldehyde , which can further oxidize to a carboxylic acid COOH

A secundary alcohol has the OH group in the middle of a chain, so the C has only one extra H: CHOH
After oxidation this will be a ketone : C=O

How to make them in the lab: You can make use of Cr(VI) compounds, like potassium dichromate. In the case of making aldehydes, the amount must be carefully mastered, or too much of the carboxylic acid will form.