# How it is possible to rank radical stability?

Oct 2, 2015

The stability of radicals on the carbon atom increase with the increase of its degree (${1}^{s t} , {2}^{n d} \mathmr{and} {3}^{r d}$).

#### Explanation:

The stability of radicals on the carbon atom increase with the increase of its degree (${1}^{s t} , {2}^{n d} \mathmr{and} {3}^{r d}$).

For example, ${R}_{3} C \cdot$ is more stable than ${R}_{2} H C \cdot$ which is more stable than $R {H}_{2} C \cdot$.

Alkyl groups are consider electron donating groups through inductive effect , and this will increase the stability of the radical in a similar way the stabilizes a carbocation.

Image source: Organic Chemistry-Janice Gorzynski Smith 3rd Ed .