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What are the factors that influence the intensity of an IR absorption band?

1 Answer
Jan 18, 2015

The most important factor that influences the intensity of an IR absorption band is the change in dipole moment that occurs during a vibration.

For example, an aldehyde C=O stretch usually occurs near 1730 cm⁻¹. An alkene C=C stretch usually occurs near 1650 cm⁻¹.

The C=O stretch is much more intense than the C=C stretch. The C=O bond is highly polar, so its dipole moment changes considerably as the bond stretches (#µ = ε × d#).

Butyraldehyde has an intense C=O absorption at 1731 cm⁻¹.

orgchem.colorado.edu

In contrast, the C=C absorption in 2,3-dimethylbut-2-ene is not detectable.

www.chemicalbook.com

The C=C bond is nonpolar, and the molecule is symmetrical, so there is no change in dipole moment during the stretch.

You can see the C=C stretch in a terminal alkyne such as oct-1-ene.

chemwiki.ucdavis.edu

The bond is not completely symmetric, so there is a small change in dipole moment. But the C=C peak at 1644 cm⁻¹ is still quite weak.