Questions asked by alila

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• why are the energies below different ? both are just breaking the same type of bond: ONCl --> NO + Cl >H= 158 kj mol-1 NCl3 --> NCl2 + Cl >H= 375 kj mol-1
  
• What is linear combination of atomic orbitals for CO2?
  
• Draw the diagrams for #"NO"_2^-#, #"NO"_2^+#, and #"NO"_2#. The HOMO of #"NO"_2^-# shows it is somewhat anti-bonding. Would you expect the nonbonding electron pairs on nitrogen or oxygen to be more reactive? Discuss
  
• why [CuCl4]2- has a flattened tetrahedral structure, not regular tetrahedron and [CoCl4]2- is tetrahedron?
  
• Discuss the following structure (η5-C5H5)(PPh3)Ir(η2-NCC6H4Cl). What is somewhat unique about the structure?
  
• What is the electron count for these complexes??