How do anhydrides react with water?

1 Answer
Jul 30, 2017

Hydrolysis

Explanation:

Hydrolysis is the simplest answer. Water hydrolyzes anhydrides into their corresponding carboxylic acids.

Note that when this happens, you get two carboxylic acids. An example of this is water hydrolyzing acetic anhydride. Acetic acid will result from the reaction. With symmetric anhydrides (like acetic anhydride), you get twice the acid equivalent.

enter image source here
Source:
http://alevelchem.com/aqa_a_level_chemistry/unit3.4/s3405/03.htm

If the anhydride is part of a ring, the ring will open, producing one molecule with two carboxylic acid groups (its corresponding acid). An example of this is water hydrolyzing succinic anhydride to form succinic acid.

enter image source here
Source:
https://goo.gl/images/z7X6U4

Hope this helps!