In which of the following compounds does the central atom exhibit #"sp"^2# hybridization?

#"CO"_2#
#"CO"#
#"SO"_2#
#"N"_2"O"#

1 Answer
Stefan V.
Oct 21, 2015

Sulfur dioxide, #"SO"_2#.

Explanation:

The first thing to focus on is what it means for an atom to be #"sp"^2# hybridized.

This type of orbital hybridization implies that the central atom uses three hybrid orbitals, one #s# and two #p#, to either form covalent bonds with other atoms, or keep lone pairs of electrons.

http://www.mhhe.com/physsci/chemistry/carey5e/Ch02/ch2-3-2.html

On a more general note, in order for an atom to be #"sp'^2# hybridized, it must be surrounded by three regions of electron density.

So, take a look at the Lewis structures for your four compounds

  • carbon dioxide, #"CO"_2#

nonsibihighschool.org

Notice that the central carbon atom forms two double bonds with the two oxygen atoms. Single, double, and triple bonds all count as one region of electron density.

This means that the carbon atom uses two hybrid orbitals, one #s# and one #p# #-># it is #"sp"# hybridized.

  • carbon monoxide, #"CO"#

http://wps.prenhall.com/wps/media/objects/476/488316/ch10.html

Notice that the carbon atom is once again surrounded by two regions of electron density - a triple bond and a lone pair of electrons.

This means that it will use two orbitals, one #s# and one #p#, to form
two #"sp"# hybrid orbitals #-># it is #"sp"# hybridized.

  • Sodium dioxide, #"SO"_2#

The sodium dioxide molecule exhibits resonance, which is another way of saying that it can be represented by using more than one Lewis structure.

However, as far as hybridization of the central atom is concerned, you can use either one.

http://people.uwplatt.edu/~sundin/114/plso2.htm

This time, the central sulfur atom is surrounded by three regions of electron density - a single bond, a double bond, and a lone pair of electrons.

This means that the sulfur atom will use three orbitals, one #s# and two #p#, to form three #"sp"^2# hybrid oribitals #-># it is #"sp"^2# hybridized.

  • Nitrous oxide, #"N"_2"O"#

The same is true for the nitrous oxide molecule, it exhibits resonance. Once again, any of the resonance structures will work

https://commons.wikimedia.org

In all three structures, the central nitrogen atom is surrounded by two regions of electron density, which implies that it is #"sp"# hybridized.

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