What is localized pi bonding?

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What is localized pi bonding?

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Answer 1 · 2017-12-13T12:48:11

Consider $2-butylene$ $"2-butylene"$ versus $1,3-butadiene...$ $"1,3-butadiene..."$

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And so we gots.... $H_{3} C - C H = C H - C H_{3}$ $H_3C-CH=CH-CH_3$ versus $H_{2} C = C H - C H = C H_{2}$ $H_2C=CH-CH=CH_2$ . The $π - bond$ $pi-"bond"$ of the former creature is LOCALIZED between $C_{2}$ $C_2$ and $C_{3}$ $C_3$ ...and of course this could give rise to 2 geometric isomers, which are?

The $π - bonds$ $pi-"bonds"$ of the LATTER are delocalized over 4-centres...certainly addition of 1 equiv $H X$ $HX$ would give rise to $1, 4 - addition$ $1,4-"addition"$ to some extent....

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What is localized pi bonding?

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