Question #645c9

1 Answer
Apr 18, 2017

How about these?

Explanation:

(a) With #"HCN"#

The #"HCN"# adds across the α #"C=O"# group to form a cyanohydrin.

#underbrace("CH"_3"COCOOH")_color(red)("pyruvic acid") + "HCN" → underbrace("CH"_3"C(OH)(CN)COOH")_color(red)("pyruvic acid cyanohydrin")#

(b) With #"H"_2#

This is the reduction of a ketone to an alcohol.

#underbrace("CH"_3"COCOOH")_color(red)("pyruvic acid") + "H"_2 stackrelcolor(blue)("Pd"color(white)(m))(→) underbrace("CH"_3"CH(OH)COOH")_color(red)("lactic acid")#

(c) With #"CH"_3"CH"_2"OH"#

This is a standard acid-catalyzed esterification.

#underbrace("CH"_3"COCOOH")_color(red)("pyruvic acid") + underbrace("CH"_3"CH"_2"OH")_color(red)("ethanol") stackrelcolor(blue)("H"^"+"color(white)(m))(⇌) underbrace("CH"_3"COCOOCH"_2"CH"_3)_color(red)("ethyl pyruvate") + "H"_2"O"#