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Dipole-Dipole Interactions

Key Questions

  • The first thing required for there to be dipole-dipole interactions between molecules is for both molecules to have a dipole. These dipoles may be permanent (polar molecules) or temporary (instantaneous or induced dipoles in non-polar molecules).

    Permanent dipole-permanent dipole interactions

    Polar molecules have an asymmetrical electron cloud/charge distribution. This is due to an asymmetrical shape (due to lone pairs of electrons around the central atom) and/or due to the presence of polar-covalent intra-molecular bonds (electronegativity difference between the two atoms of 0.5+), which do not "cancel out" each other.

    As there is an asymmetrical charge distribution, one side ("pole") of the molecule has a slight ("delta") negative charge, while the other pole has a delta positive charge. The attraction between the delta negative pole of one molecule and the delta positive pole of a neighbouring molecule is called a permanent dipole-permanent dipole attraction.

    wps.prenhall.com
    SOURCE: http://wps.prenhall.com/wps/media/objects/3311/3391094/blb0903.html

    Temporary dipoles

    Non-polar molecules can also have temporary dipoles. These form more often when the molecule has a large electron cloud (you can predict this from its molar mass). At any one instant, the electrons may be unevenly distributed, creating an instantaneous dipole within the molecule: one pole is delta negative, while the other is delta positive. This can induce at dipole in a neighbouring molecule, creating a temporary dipole-temporary dipole attraction.

    mysite.verizon.net
    SOURCE: http://chemistrywithadoktor.blogspot.co.nz/2010_05_01_archive.html

    This idea can be used to explain why #Cl_2# is a gas, #Br_2# is a liquid (more dipole-dipole attractions), and #I_2# is a solid that sublimes (even more dipole-dipole attractions).

    centros.edu.xunta.es
    SOURCE: http://centros.edu.xunta.es/iesames/webantiga/webfq/EUSECTSUSO/chem_phys_bac/Chemistry_2/chemical_bonding.htm

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