# Introduction to Newman Projections

Organic Chemistry | Conformation of Acyclic Alkanes - Part 1/3.

Tip: This isn't the place to ask a question because the teacher can't reply.

1 of 3 videos by Dr. Hayek

## Key Questions

• A sawhorse projection is a view of a molecule down a particular carbon-carbon bond. Groups connected to both the front and back carbons are drawn using sticks at 120° angles.

It is similar to a Newman projection, but it shows the carbon-carbon bond that is hidden in a Newman projection.

Just as with Newman projections, you can draw sawhorse projections in eclipsed and staggered conformations.

Below are two sawhorse projections of ethane.

They are called sawhorse projections because the eclipsed conformation looks like a carpenter's sawhorse.

Sawhorse projections are useful for determining if two molecules are enantiomers or diastereomers.

They make it easier to see if the structures are mirror images or superimposable.

• Sawhorse projections generally show when something is antiperiplanar or synperiplanar, more easily than something like a Newman projection or a basic line structure can.

Take ethane as an example.

An antiperiplanar conformation has a ${180}^{\circ}$ dihedral angle, i.e. the atoms of interest across one bond are on opposite sides along the vertical molecular plane.

A synperiplanar conformation has a ${0}^{\circ}$ dihedral angle, i.e. the atoms of interest across one bond are on the same side along the vertical molecular plane.

A sawhorse projection approximates this 3D structure extremely well, and allows one to judge whether an $E 2$ reaction is likely to occur or not (it requires an antiperiplanar conformation).

A Newman projection would not depict the dihedral angle correctly, because one would be viewing the important atoms from the front instead of an aerial view.

Thus a ${180}^{\circ}$ dihedral angle may very well look like a ${120}^{\circ}$ dihedral angle, unless one knows the precise bond lengths of interest to recognize when the bonds are not entirely opposite to each other.

• This key question hasn't been answered yet.

## Questions

• · 6 days ago
• · 1 month ago
• · 1 month ago
• · 2 months ago
• · 2 months ago
• · 5 months ago
• · 6 months ago
• · 6 months ago
• · 9 months ago
• · 9 months ago
• · 10 months ago
• · 1 year ago
• · 1 year ago
• · 1 year ago
• · 1 year ago
• · 1 year ago
• · 1 year ago
• · 1 year ago
• · 1 year ago
• · 2 years ago
• · 2 years ago
• · 2 years ago
• · 2 years ago
• · 2 years ago
• · 2 years ago
• · 2 years ago
• · 2 years ago
• · 2 years ago